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djhouse81
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djhouse81
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djhouse81
(sorry if this problem has already been posted, but I do not feel like searching for it)

The rate of a chemical reaction is directly proportional to the square of the concentration of Chemical A and inversely proportional to the concentration of Chemical B. If the concentration of Chemical B is increased by 100%, which is closest to the % change in concentration of Chemical A required to keep the reaction unchanged.

A) 100% decrease
B) 50% decrease
C) 40% decrease
D) 40% increase
E) 50% increase

OA is D


You know, if you didn't post OA, I would have done this quesiton incorrectly. So thanks for that, now I have to remember the "inversely" proportional better.

Set r = rate, a = concentration of a, b = concentration of b, c = constant
r = c * a^2
r = (1/c) * b
increase b by 100%...you have
r = (1/c) * 2b
=> r/2 = (1/c) * b
Plug in r/2 for equation for a:
r/2 = c * a^2
=> r = c * (sqrt(2) * a)^2
=> r = c * (1.4 * a)^2
Increase by 40%!!!
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bkk145
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Just to let you know, my problem before was thinking that "inversely proportional" means this:

r = 1 / b which is incorrect.

The equation for "inversely proportional" is

r = (1/c) * b
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djhouse81
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Thank you for the help. I hope I never see that type of problem on the real thing, but if I do I will know to use a constant in the equation.

It goes to show that without an error log, I would never know where I went wrong, and that could have come back to haunt me on the real thing.
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R = k(A^2/B ) where k is a constant

B increases by 100%, so now R = k(A^2/2B)

To keep the rate constant, we need 2A^2, which can be written as sqrt(2)A * sqrt(2)A. So A needs to increase by 41% ( which is 1-sqrt(2)).
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40 % increase

Rate = A^2/B

A1^2/B = A2^2/2B

A2^2 = 2A1^2

A2 = 1.41A1

0r 41% increase, approx. 40% increase



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