You can notice that if you roll a '1' on the first die, the second number is always a multiple of your first roll, and if you roll anything else on the first die, there will always be at least two numbers you can roll on the second -- you can roll the same number again, or you can roll 1. So the answer clearly must be larger than 2/6, and only answer A is remotely plausible.
It's slightly tedious to get the answer without choices, but there are lots of ways to go about breaking down the cases. This might not be the fastest, but one way: we have 6*6 = 36 possible rolls of two dice, if we think about rolling them one at a time. In 11 of those, one of the rolls is a '1' (not 12, because we don't count 1, 1 twice), and then one roll is certainly a multiple of the other. In 5 more of the rolls, one is a '2' and the other is 2, 4 or 6 (again we don't count 2, 2 twice). In 3 more rolls, one roll is a '3' and the other is a '3' or a '6'. Then we also have three further possibilities, where we roll two 4's, two 5's or two 6's. Adding up all the possibilities, we can get two rolls where one is a multiple of the other in 11 + 5 + 3 + 3 ways, or 22 ways, so the answer is 22/36 = 11/18.