Hi Hong Hu,
I think this is how to approach the problem:
R red balls and W white balls.
Probability of picking W on the kth pick ==> Till k-1 picks you only picked R balls and only on the kth pick you picked the white ball.
since this is a general problem without involving any numbers the answer will have to be in a series like expression.
Now lets give index to our k.
Say k = 1 ==> On the very first pick you get W
P(k) = P(1) = W/(R+W)
Say k=2
P(k) = P(2)= R/(R+W)*W/{(R-1)+W}
Say k=3
P(k) = P(3) = R/R+W*(R-1)/{(R-1)+W}*W/{(R-2)+W}
For k > 3
P(k) = R(R-1)..(R-(k-2))W/(R+W)(R-1+W)(R-2+W)..(R-(k-1)+W) And this is a product series.
Anirban