Fairly straightforward. We have x^4 as the largest, hence the first conclusion I drew straightaway was x should be negative. Next, look at x^5 > x^3. This tells me that it should be a negative fraction, since negative integers mean x^5 would be less than x^3 (e.g. (-2)^5 = -32 and (-2)^3 = -8). The only negative fraction we have is -2/3 so I go with that.
Double checking, x = -2/3, then x^4 = 16/81, x^5 = -32/243, x^3 = -8/27
Indeed, here x^4 > x^5 > x^6
If the latter is tougher to derive mentally (like it is for me), I typically think about (-1/2)^1 = -1/2 = -0.5 and (-1/2)^3 = -1/8 = -0.125. The latter is closer to 0 on the number line, hence must be greater -> higher power of a negative fraction > lower power
(There are probably simpler ways of doing this, but this approach made the most intuitive sense to me right away without using any real manipulations or complex theory)