The key insight to greatly simplify the calculation in this problem is realising that since we are not given any specific values of any of the angles in this question, and since it is a PS question with one correct answer in all possible cases of the star, the correct answer would hold true irrespective of what the angles of the pentagon in the star, and the corresponding vertices of the star are. Thus, to simplify our calculation, we may assume it to be a regular pentagon.
In such a case, for any polygon with n sides, the sum of the interior angles = (n-2)*180. Therefore, the sum of the angles inside the pentagon = (5-2)*180 = 540. Because we assume it to be a regular pentagon, each individual angle is 108 degree for each interior angle.
Further, since complementary angles on a straight line must sum to 180 degrees, Each of the external adjacent angle (which also represent one of each of the angles of triangle adjacent to the internal pentagon) must be 180-108 = 72.
The sum of the angles inside each of these triangles is 180. Thus each point of the star to be 180-72-72 = 36.
Since the star has 5 points, the sum of the angles of all of the 5 points as required in the question is 5*36 = 180.