Work rate problem, and I actually like this one because the setup trips a lot of people even though the algebra is short.
1. Let N's time alone = n hours. The problem says M takes 3/4 of N's time, so M's time alone = (3/4)n hours. Notice M is faster than N here, since it takes less time.
2. Rates add when things work together. Rate of M = 1/((3/4)n) = 4/(3n). Rate of N = 1/n.
3. Combined they finish in 6 hours, so combined rate = 1/6. Set up: 4/(3n) + 1/n = 1/6.
4. Common denominator on the left: 4/(3n) + 3/(3n) = 7/(3n). So 7/(3n) = 1/6, which gives 3n = 42, so n = 14.
5. That's N's time alone, exactly what's being asked. Answer is E, 14 hours.
The trap here, at least the one I fell into the first time I saw this style question, is reading "3/4 of the time" and just assuming that means multiply 6 by something simple to land on 12. It's tempting because 12 is sitting right there as answer D and it "feels" like the round number a work problem should spit out. But GMAT rate problems basically never let you skip setting up the actual rate equation, there's no shortcut that avoids the fractions.
Quick check: plug n=14 back in, M's time is 10.5 hours, rate 2/21, N's rate is 1/14 which is 1.5/21, add them and you get 3.5/21 = 1/6. Checks out.
One-liner: whenever you see "X takes a fraction of the time Y takes," translate that into an actual rate before you touch the combined-rate equation, don't try to shortcut it in your head.