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I have a concern in option A with the first "it".
the said it is as well in the underlined portion of the sentence and we can never rule out the possibility or a path there. It therefore becomes difficult to assume that the stated "it" is correct and correctly refers to the singular language!
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A. and the sub-languages or dialects within it, but those who have tried to count typically have found
I don't love the sound of this answer choice, but
SC isn't ever about sound, so... whatever.
The "it" is perfect here. What are the singular nouns that precede "it"? "A language" is the only reasonable option -- and that makes perfect sense. "Those" generally works better with an antecedent of some sort, but it's basically just a synonym for "people" here, and that's acceptable. Keep (A).
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B. and the sub-languages or dialects within them, with those who have tried counting typically finding
"Them" is confusing: does it refer to "dialects", "sub-languages," or all the way back to "languages" at the beginning of the sentence? I also can't figure out why we would want to conjoin these phrases with "with" -- that doesn't make much sense. (A) is much better, so (B) is out.
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C. and the sub-languages or dialects within it, but those who have tried counting it typically find
I'm cool with the first "it", but the second "it" doesn't work: "those who have tried counting the language..."? We're trying to count languages, and that needs to be plural. Eliminate (C).
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D. or the sub-languages or dialects within them, but those who tried to count them typically found
Same problem with "them" as in answer choice (B). Plus, I don't see any good reason to use past tense here. The use of present perfect in (A) makes more sense, since people have presumably attempted to count languages in the past, and continue to do so in the present. (D) is gone.
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E. or the sub-languages or dialects within them, with those who have tried to count typically finding
Just a hybrid of the worst elements of (B) and (C). (E) is out, and (A) is correct.