Algebraic approach:
Let A=# of 1c coins, B=# of 5c coins, C=# of 10c coins, D=# of 25c coins, E=# of 50c coins.
(1) A+5B+10C+25D+50E=100 (Cent value of coins)
I.
(2) A+B+C+D+E=91 (Total number of coins)
Subtract equations (1)-(2): 4B+9C+24D+49E=9
Equation will work if B=0, C=1, D=0, E=0; i.e. one 10c coin. Can then solve for A using equation (2), A+0+1+0+0=91, A = 90 (# of 1c coins).
II.
(2) A+B+C+D+E=81 (Total number of coins)
Subtract equations (1)-(2): 4B+9C+24D+49E=19
From a quick glance, no combination of B,C,D,E will fit into the equation. Thus, eliminate II.
III.
(2) A+B+C+D+E=76 (Total number of coins)
Subtract equations (1)-(2): 4B+9C+24D+49E=24
Equation can work if B=0, C=0, D=1, E=0; i.e. one 25c coin. Can then solve for A using equation (2), A+0+0+1+0=76, A = 75 (# of 1c coins).
Equation can also work if B=6, C=0, D=0, E=0; i.e. six 5c coins. Can then solve for A using equation (2), A+6+0+0+0=76, A = 70 (# of 1c coins).