How I think about this questions...
Start with (2). The tens digit of XY means that both X and Y MUST have a tens digit of 2. Therefore:
X = 121, 221, 122, or 222
and
Y = 121, 122, 221, or 222
121/3 has remainder of 1.
221/3 has remainder of 2.
122/3 has remainder of 2.
222/3 has remainder of 0.
Not sufficient.
At this point you know the answer must be (A) or (C) or (E), but
not (B) or (D).
Now if you consider (1), forgetting (2), that leaves only the pair {X=121 and Y=121} (you need the ten's digit in both to be 2 and the one's digit in both to be 1).
X can only be one number, 121, so the remainder is 1.
I think the answer is (A), (1) is sufficient.
The GMAT is made to test you on problems you haven't seen before. It's supposed to be tricky - a reasoning test - not a "can you learn how to follow a procedure" kind of math. Start thinking about these kinds of questions more analytically.