Brent is completely right - you don't need to know a thing about playing cards for the GMAT. This particular question is probably of more interest to poker players than to GMAT test takers (at least in poker variants like hold'em where you start with two cards). If you want to know the probability of getting any specific unpaired hand, like queen-jack or ace-three, then, using queen-jack as in the question, our first card can be any of the 8 queens or jacks, so the probability is 8/52 that our first card is one of the ones we want, and then there will be 4 cards left that complete our queen-jack hand, and we'll be picking our second card from 51, so the probability our second card is what we want is 4/51, so the answer is 8/52 * 4/51 = 8/(51*13) = 8/663 ~ 1.2%.
Or you could look at things this way: the probability you get a pair when dealt two cards is 3/51 (once we know our first card, 3 out of the 51 remaining cards will pair it), or 1/17. So the probability we do not get a pair is 16/17. Each specific unpaired hand is equally likely (you're as likely to get ten-three as ace-king), and there are 13C2 = (13*12)/2! = 13*6 different unpaired hands that are possible, so the probability we get some specific unpaired hand like queen-jack is (16/17)*(1/13C2) = 16/(17*13*6) = 8/663.