I selected C - 145 minutes.
We want to minimize the time that it takes for the hiker to travel 10km.
Let's have him start at the faster pace, but lets make sure we understand how many oxygen cannisters he is using per kilometer and per hour.
Slow Pace: 4 km/hr; 2 cannisters/km, effectively: 8 cannisters/hour
Fast Pace: 5 km/hr; 1.3*2 cannisters/km = 2.6 cannisters / km, or 13 cannisters / hour.
Our constraint is the number of cannisters which is 25, which prevents us from traveling the entire 10 kms in 2 hours at the faster pace because we do not have enough cannisters.
Lets travel the first 5kms in 1 hr at the faster pace, leaving us with 12 cannisters.
Let's say we continue to travel at the faster pace and use as many cannisters as we can to go 4 more kms at the faster pace, spending 48 more minutes and 10.6 cannisters, leaving us with 1.4 cannisters and 1 km to go. At this point our slowest option requires 2 cannisters / km so we need to rest in order to refill on cannisters. After the 25 min rest, we are at 60 + 48 + 25 = 133 minutes, with 1 km to go. We can travel again at the faster pace, using 12 minutes to get there, for a total of 145 minutes.
However, what if, after 5kms, we used the slower pace? With 12 cannisters and 5 km to go, we could travel for 1.5 hrs at the 4 km/hr pace and it would only take us 75 minutes to travel 5kms while using 10 cannisters. 60 + 75 = 135 minutes. This is not an answer choice. Can someone explain why?