Let's assign ranks to each letter based on their alphabetical order:
C F O S U
1 2 3 4 5
Now, for words starting with C (the first ranking letter) the remaining words can be arranged in 4! ways = 24 ways (since we know C's position is fixed).
Now, for the next ranking letter, F, the following letter should be C, because we are looking at alphabetical order. Thus, given that F and C are fixed, the remaining 3 letter can be arranged in 3! ways = 6 ways.
Note, that we are making our way down the list by taking factorials for each arrangement.
Now we have to look at words starting with FO. When F O are in a fixed position, the next letter to consider should be C, since we are following the alphabetical order. When F O C are in a fixed position, the remaining two letters can arrange themselves in 2! ways = 2 ways.
Note that FOCUS will be the last word if we follow the alphabetical order, since after F O C, S should come before U creating the word FOCSU. After that, only FOCUS remains.
Thus to reach FOCUS we had to go through 24 + 6 + 2 = 32 words. Thus, FOCUS is on the 32nd position.