once you factorize the equation to 1/a+1/b=2/3, its pretty self explanatory that 3,3 will be a pair.
the only other way to get a 3 in denominator will be if 4/6, 6/9, 8/12...
and to get 4/6,6/9,8/12, on of the fractions has to be 1/6,1/9,1/12, which means the other would have to be 3/6,5/9,7/12. here since the numerator has to be 1, 3/6 works since that can get factored to 1/2, but the others cant.
i can't prove this but you need realize that every fractions numerator is going up by 2 and denominator by 3 so you'll just keep getting 9/15,11/18,13/21... none of can be factored to a one on top. so you're stuck with three pairs.
The other intuitive (i'm sure someone figured that out) would be to know that you got one pair 3,3 and then 2,6, 6,2. so your answers can only be A or B, but it's not possible to get another identical pair like 3,3, so you can't have 6 pairs.