If you break down this argument:
Sentence 1 is background information telling us that this doctor recommends supplements.
Sentence 2 is the evidence for the conclusion: the doctor is acting in self interest! Notice, too, that the supplements aren't mentioned here...just the doctor.
Sentence 3 is the conclusion: therefore, we shouldn't use these supplements.
So if we're looking for a flaw in reasoning, it has to do with Sentence 2, or how 2 interacts with 3.
Look at what's missing between 2 and 3 - the only piece of evidence for "don't use the supplements" is "the doctor acts in self-interest." The major premise never mentions the supplements! All it does is mention how the doctor is motivated. And that's the flaw: the conclusion says that you shouldn't use supplements, but its only evidence is about the motives of one person who recommends the supplements - we don't have any evidence that the supplements are ineffective (or bad for any other reason). And that's what D tells us.