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A. As well as getting away unscathed, Kim managed to gather valuable knowledge about orchids and bring home scores of rare specimens
- not definitely wrong (IMHO), so let's keep and search for a better option
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B. Besides getting away unscathed, Kim also managed to gather valuable knowledge about orchids and bring home scores of rare specimens
- "also" leads to redundancy, as we've already had "besides"
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C. Besides getting away unscathed, also Kim managed to gather valuable knowledge about orchids and bring home scores of rare specimens
- wrong for the same reason as B
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D. Kim not only got away unscathed, but also managed to gather valuable knowledge about orchids and bring home scores of rare specimens
- nice, concise way to present sme meaning as in original sentence. I'll vote for D
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E. Kim got away not only unscathed, but also managed to gather valuable knowledge about orchids and bring home scores of rare specimens
- not only X but also Y construction requires X || Y; not the case in E, so eliminate
D is a correct choice